| Reference: | Burke, S. D.; Murtiashaw, C. W.; Saunders, J. O.; Dike, M. S. J. Am. Chem. Soc. 1982, 104, 872. DOI |
| Keywords: | Enone -> Allyl-OH Jones oxidation Aldehyde -> CarboxAcid CarboxAcid -> CarboxCl Alkene cleavage Ketone -> Ketal Wharton transposition Aldehyde -> Enolacetate Alkene cleavage Jones oxidation Ketal -> Ketone Aldehyde -> CarboxAcid CarboxAcid -> CarboxEster Claisen-Enol ether Si-Vinyl+Acyl-X Friedel-Crafts Acylation, Ene Epoxidation, nucleophilic Enone Claisen-Enol ether Li-Vinyl+Ketone Enone+Li-R Enone-β-OR -> Enone Stork-Danheiser Hydrogenation Alkene CompRed-Alkene/Aldehyde+H2 Aldol-Na -> Enone Aldehyde enamine+Enone Enone+Enamine ConjAdd Enamine Lemieux-Johnson oxidation CompOx-Alkene/Enone+OsO4 Mechanism CompNu-Si-Vinyl/Alkene+Acylium |
| Reagents: | Hg(OAc)2 Hg(OAc)2 Vinyl-OR Vinyl-Li AlH4-Li+ CrO3, H2SO4 (Jones) Oxalyl chloride TiCl4 OsO4, NaIO4 NMO Hydroxide, sodium 18-cr-6 Glycol Hydroperoxide, tbutyl Hydrazine Acetic acid Acetate, potassium OsO4, NaIO4 H2, Pd CrO3, H2SO4 (Jones) Diazomethane Vinyl-OR Morpholine |