| Reference: | Schiehser, G. H.; White, J. D. J. Org. Chem. 1980, 45, 1864. DOI |
| Keywords: | Birch reduction • Simmons-Smith • Fischer esterification • Enone -> Ketal(Me) • Enone -> Ketal(Me) • CarboxEster -> Alkyl-OH • Alkyl-OH -> Aldehyde • Allyl-OH -> Enone • Diazoester Cyclopropanation • Mg-Vinyl+Ketone • Mg-Vinyl+Aldehyde • Ketal -> Vinyl-OR • Hydrogenation Diene • Cyclopropane opening • Diels-Alder, Intram • |
| Reagents: | CH2I2, Zn/Ag • HCl • Orthoformate • AlH4-Li+ • DMSO, Py·SO3 • DMSO, Py·SO3 • Vinyl-MgX • Propenyl-MgX • DMSO (solvent) • H2, Pt • Diazoacetate • |