| Reference: | Yamamoto, H.; Sham, H. L. J. Am. Chem. Soc. 1979, 101, 1609. DOI |
| Keywords: | Enone -> Allyl-OH O-H -> O-THP O-THP -> O-H Ketone -> Ketal Corey-Kim Ketone -> Oxime Ketal -> Ketone Imine -> Amine Claisen-Enol ether Allylic oxidation -> Enone Mg-Vinyl+Aldehyde Hydrogenation Diene Li-Vinyl+Ketone Reductive amination, Al-H Amine -> Isocyanide Enone -> Enolsilane Dehydration -> Ene Oxime -> Amine Diels-Alder, Intram |
| Reagents: | AlHiBu2 Vinyl-OR Vinyl-MgX DHP CrO3·Py2 (Collins) LiNiPr2 SiMe3-Cl Acetic acid Glycol Me2S·Cl2 Propenyl-Li MeSO2Cl, NEt3 H2, Ir NH2OH TiCl3 Acetic acid AlHiBu2 Formic acetic anhydride TsCl, Py Hg(OAc)2 AlHiBu2 |