| Reference: | Kigoshi, H.; Imamura, Y.; Niwa, H.; Yamada, K. J. Am. Chem. Soc. 1989, 111, 2302. DOI |
| Keywords: | CarboxEster -> CarboxAcid • CarboxAcid -> CarboxCl • CarboxEster -> Alkyl-OH • Allyl-OH -> Enone • O-H -> O-SiMe2tBu • Alkene isomerization • Ketone -> Ketone-α-SeR • Alkyl-OH -> Ketone • Ketone -> Enolsilane • Enolsilane -> Ketone enolate • Alkyl-OH -> Aldehyde • O-SiMe2tBu -> O-H • Friedel-Crafts Acylation, Ene • Ketone enolate+Me-I • Selenoxide-Ei -> Enone-5 • Ketone -> Enone • Enone enolate dialkylation, spiro • Deconjugative alkylation • CarboxEster enolate+Alkyl-X • Epoxidation, nucleophilic Enone • Mg-Alkyl+Ketone • Ketone -> Ketone-α-SeR • Epoxide reduction • Decarbonylation • Hydroperoxide -> Alcohol • Ketone epimerization • Cyclopropane • |
| Reagents: | LiNiPr2 • Allyl-Cl • Diazomethane • Hydroxide, potassium • Oxalyl chloride • SnCl4 • AlH4-Li+ • Cr2O7·2ImH • SiMe2tBu-Cl • Ethylene dichloride • KOtBu • LiNiPr2 • H2O2 • H2O2, NaOH • Ca°/NH3 • MeMgI • DMSO, (COCl)2 • LiNiPr2 • Fluoride, Bu4N+ • MeI • AlH4-Li+ • DMSO, (COCl)2 • Fluoride, Bu4N+ • O2 • PPh3 • SePh-Cl • SiMe3-Cl • Imidazole • KOtBu • |