| Reference: | Corey, E. J.; Ensley, H. E. J. Am. Chem. Soc. 1975, 97, 6908. DOI |
| Keywords: | CarboxEster -> Alkyl-OH • Diol-1,2 cleavage • Baeyer-Villiger • Iodolactonization • Ketone -> Alkyl-OH • Cu-Aryl+Enone • Enone+Cu-Aryl • ConjAdd Cu-R • CarboxEster enolate oxidation • CarboxEster -> CarboxEster-α-OH • Cyclopentadienide+Alkyl-X • Diels-Alder, EnoateEster(asym) • Ketone epimerization • Chiral auxiliary • |
| Reagents: | Cl-CH2-OR • LiNiPr2, O2 • P(OEt)3 • AlH4-Li+ • Periodate, sodium • H2O2, NaOH • I2, KI • Bicarbonate, sodium • Aryl-MgX • CuCl • Hydroxide, potassium • Na°, iPrOH • Acryloyl-Cl • Cyclopentadienide • Acrylate • AlCl3 • |