| Reference: | Tanaka, T.; Toru, T.; Okamura, N.; Hazato, A.; Sugiura, S.; Manabe, K.; Kurozumi, S.; Suzuki, M.; Kawagishi T.; Noyori, R. Tetrahedron Lett. 1983, 24, 4103-4104. DOI |
| Keywords: | O-SiMe2tBu -> O-H • Radical reduction(C-NO2) • Alkyl-NO2 -> Alkyl-H • Enone -> Allyl-OH(asym) • O-H -> O-SiMe2tBu • Cu-Vinyl+Enone • ConjAdd-Michael • Ketone enolate+Vinyl-NO2 • Vinyl-NO2+Enolate • |
| Reagents: | HSnBu3 • AIBN • HF·Py • BINAL-H • SiMe2tBu-Cl • Vinyl-NO2 • |