| Reference: | Smith, A. B. III; Kim, D. S. Org. Lett. 2005, 7, 3247. DOI |
| Keywords: | N-H -> N-SO2R • Li-Me+CarboxEster • CarboxEster+Li-R • Ketone -> Ketal • O-H -> O-SiPh2tBu • Ketal -> Ketone • Amine-6 • Aldehyde -> Alkyl-OH • Ketal(thio) -> Ketone • CarboxEster -> Ketone • B-Allyl-Ipc+Aldehyde • Aldol-B-Ipc • Mitsunobu -> Aziridine • Alkyl-OH -> Alkyl-NR2 • Aziridine • RCM -> Ring-N • Wittig-methoxymethyl • Reductive formylation • Wittig-methyl • Alkene isomerization • Alkyl-OH -> Alkyl-H • Diol -> Epoxide • CompE+-CarboxEster/Aziridine+Li-R • O-SiMe2tBu -> O-H • Li-Dithiane+Epoxide • Li-Dithiane+Aziridine • N-H -> N-Alkyl(2°) • Amine-6 • |
| Reagents: | TsCl, NEt3 • PPh3, DEAD • Aziridine • MeLi • SiMe3-OTf • Aziridine • BF3·OEt2 • H2O2, NaOH • SiPh2tBu-Cl • Camphor sulfonic acid • NaH • Epoxide • HCl, H2O • LiN(SiMe3)2 • Grubbs II • PPh3=CH-OMe • HCl • BH4-Na+ • MeSO2Cl, NEt3 • BHEt3-Li+ • Iodosobenzene-TFA • PPh3=CH2 • TsOH • Crotyl-B(Ipc)2 • SiMe3-Cl • Imidazole • BuLi(n) • Fluoride, Bu4N+ • MeSO2Cl • Na(Hg) • |