| Reference: | Helm, M. D.; Da Silva, M.; Sucunza, D.; Findley, T. J. K.; Procter, D. J. Angew. Chem. Lett. 2009, 48, 9315. DOI |
| Keywords: | Mg-Vinyl+Enone • Enone+Mg-Vinyl • O-H -> O-C(O)R • O-TBS -> O-H • Alkyl-OH -> Aldehyde • O-H -> O-TBS • O-C(O)R -> O-H • Alkyl-OH -> Ketone • Ketone -> Ketal • CarboxEster -> Alkyl-OH • Diol -> Ketal • ConjAdd-Triflation • Pd-Carboxylation • Si-Allyl+Aldehyde • CarboxEster enolate+Aldehyde • Ketyl+Enone • Hydrogenation Alkene(asym) • |
| Reagents: | Vinyl-MgX • CuI • Tf2N-2-Py-5-Cl • Pd(OAc)2 • CO • BF3·OEt2 • DMAP • HF·Py • SmI2 • SiMe2tBu-OTf • AlH4-Li+ • H2, Pd • Glycol • Orthoformate • AlH4-Li+ • Me2C(OMe)2 • Camphor sulfonic acid • DMAP • |