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Total synthesis of Pleraplysillin-1:
Reference: Scott, W. J.; Crisp, G. T.; Stille, J. K. J. Am. Chem. Soc., 1984, 106, 4630. DOI
Keywords: Ketone → EnolTriflate • ConjReduct-Triflation • ConjReduct Enone • Cu-Vinyl+Alkyl-X • Allyl-X+Cu-R • Pd/Sn-Vinyl+Vinyl-X •
Reagents: BH(sBu3)-Li+ • Tf2NPh • Pd(PPh3)4 • Chloride, lithium •

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