| Reference: | Posner, G. H.; Hatcher, M. A.; Maio, W. A. Org. Lett. 2005, 7, 4301. DOI |
| Keywords: | Enolsilane -> Ketone enolate • O-H -> O-SiMe2tBu • Lactone-10 • O-H -> O-C(S)OR • Ketone enolate+Epoxide • Epoxide+Enolate • Grob fragmentation - oxidative • Enolsilane -> Ketone enolate • Ketone enolate+Oxetane • Lactone-8 • Alkyl-OH -> Alkyl-H(2°) • |
| Reagents: | MeLi • Epoxide • BF3·OEt2 • Iodosobenzene-OAc • I2 • Fluoride, Bu4N+ • S=C(OPh)Cl • HSnBu3 • AIBN • MeLi • Oxetane • BF3·OEt2 • |