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Total synthesis of Phorocantholide J:
Reference: Petrzilka, M. Helv. Chim. Acta 1978, 61, 3075. DOI
Keywords: Ketone → Alkyl-OH • Selenoxide-Ei → Enol ether • Selenoetherification • Ether-8 • Claisen-Ketene acetal • Lactone-9+ • Li-Alkyl+Aldehyde • Enal+Li-R • O-H → O-Vinyl •
Reagents: BH4-Na+ • Vinyl-OR • Alkyl-Li • Li°Naphth • Acrolein • SePh-Br • NEtiPr2 • Periodate, sodium • Sulfate, magnesium • Hg(OAc)2

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