| Reference: | Rigby, J. H.; Sidique,S. Org. Lett. 2007, 9, 1219 DOI |
| Keywords: | Japp-Klingemann • Imine -> Amine • N-H -> N-Me • Ketal(thio) -> CH2 • O-H -> O-C(O)NR2 • Carbene Cycloaddition • Carbene, bisphenylthio • Lactam-5 • Curtius • C-CO2H -> C-N • 1,1-Dipolarophile • CarboxAmide -> Amine • N-H -> N-Me • Fischer Indole • Indole synthesis • |
| Reagents: | Nitrite, sodium • Hydroxide, potassium • HCl • MeI • Hydroxide, lithium • Azide, diphenylphosphoryl • AlH4-Li+ • MeI • RaNi • AlH4-Li+ • BBr3 • Isocyanate • DMF (solvent) • |