image

Total synthesis of Pentenomycin I (Carretero):
Reference: Rodriguez Rivero, M.; de la Rosa, J. C.; Carretero, J. C. J. Am. Chem. Soc. 2003, 125, 14992-14993. DOI
Keywords: O-SiPr3 → O-H • Sulfoxide-Ei → Enone • Ketone → Enone • Pauson-Khand • Cyclopentenone • Alkene → Diol-1,2 •
Reagents: OsO4 • EneSulfoxide • NMO •

Syntheses Home