| Reference: | Paquette, L. A.; Geng, F. Org. Lett. 2002, 4, 4547 DOI |
| Keywords: | O-H -> O-C(O)R • Ketone -> Alkyl-OH • O-H -> O-C(O)R • Aldol-Li -> Aldol • Ketone enolate+Ketone • Ketone enolate+Me-I • Alkyl-OAc -> Alkyl-H • Mechanism • ConjReduct Enone • ConjReduct-Elimination • Ketone-α-OR -> Ketone • Electrocyclic-4π • Electrocyclic-8π • Li-Vinyl+Ketone • Enone+Li-R • Li-Alkynyl+Ketone • Enone+Li-R • Li/H -> Li-Alkynyl • |
| Reagents: | DMAP • Li°/NH3 • Li°/NH3 • KOtBu • MeI • Li°/NH3 • DMAP • Na° • HMPA (solvent) • Vinyl-Li • Alkynyl-Li • |