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Total synthesis of Peduncularine (partial):
Reference: Washburn, D. G.; Heidebrecht, R. W.; Martin, S. F. Org. Lett. 2003, 5, 3523. DOI
Keywords: CarboxAmide → Imine • Lactam enolate+Alkyl-X • Alkyl-X+Enolate • Mg-Vinyl+Imine • Iminium+Mg-R • RCM → Ring-C •
Reagents: BH4-Na+ • HCl, EtOH • Sulfinic acid, benzene • Chloride, calcium • Vinyl-MgX • Vinyl-ZnX • LiNiPr2 • Allyl-Br • Grubbs II • H2SO4

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