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Total synthesis of Pareitropone:
Reference: Feldman, K. S.; Cutarelli, T. D. J. Am. Chem. Soc. 2002, 124, 11600. DOI
Keywords: CarboxAcid → Alkyl-OH • O-H → O-SiPh2tBu • Alkyl-OH → Aldehyde • O-SiPh2tBu → O-H • Mitsunobu → Amine • Alkyl-OH → Alkyl-NR2 • O-SiiPr3 → O-H • Li/H → Li-Aryl • Epoxide+Li-R • Li-Aryl+Epoxide • Li-Diazomethane+Aldehyde • Sn-Alkynyl → Alkynyl-iodonium • Aldehyde → Alkyne • Quinoline synthesis • Tropone synthesis • Carbene Cycloaddition • Mechanism • Mg-Aryl+Aryl-OMe • Alkynyliodonium • Amine-6 • Mechanism •
Reagents: BuLi(n) • Epoxide • AlH4-Li+ • Cr2O7·2PyH (PDC) • LiNiPr2 • HF • BuLi(n) • Alkynyl-SnR3 • Iodosobenzene-cyanotriflate • Fluoride, potassium • O2 • Diazomethane, silyl • PPh3, DEAD • SnBu3-Cl • LiN(SiMe3)2 • Aryl-MgX • Aryl-Li •

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