| Reference: | Schmitz, W. D.; Messerschmidt, N. B. J. Org. Chem. 1998, 63, 2058. DOI |
| Keywords: | Ketal(thio) -> CH2 • O-Bn -> O-H • Alkyl-OH -> Aldehyde • CarboxEster -> CarboxAmide(Weinreb) • O-H -> O-SiMe2tBu • Ketone -> C=CH2 • O-SiMe2tBu -> O-H • Alkyl-OH -> Aldehyde-α-OR • O-Bn -> O-H • Lactone-5 • Takai-Utimoto -> Vinyl-I • Mg-Alkyl+CarboxAmide(Weinreb) • CarboxAmide(Weinreb)+Mg-R • Carboalumination Alkyne • Pd/Zn-Vinyl+Vinyl-X • Negishi coupling • CarboxEster(thio) enolate+Aldehyde • Lactone-4 • Mukaiyama Aldol • Aldol-Si • Ketene acetal+Aldehyde • Aldehyde+Enolsilane • Li/H -> Li-Dithiane • Li-Dithiane+Alkyl-X • Li-Dithiane+Alkyl-X • |
| Reagents: | RaNi • Ca°/NH3 • DMSO, (COCl)2 • NMe(OMe)-AlMe2 • SiMe2tBu-Cl • Alkyl-MgX • Mg° • Tebbe • Fluoride, Bu4N+ • DMSO, (COCl)2 • BCl3 • AlMe3 • CHI3 • Pd2(dba)3 • ZrCp2Cl2 • ZnCl2 • BuLi(tert) • |