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Total synthesis of Nuciferal:
Reference: Büchi, G.; Wüest, H. J. Org. Chem. 1969, 34, 1122. DOI
Keywords: Aldehyde → Acetal • Acetal → Aldehyde • Aldehyde → Imine • Imine → Aldehyde • Hydrogenolysis C-OR • Aldehyde azaenolate+Aldehyde • Dehydration → Enal • ConjAdd M-X • Ketone+Mg-Alkyl • Mg-Alkyl+Ketone •
Reagents: Glycol • HBr • Alkyl-MgX • Mg° • H2, Pd • HCl, H2O • NH2tBu • LiNiPr2 • Oxalic acid • Acrolein •

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