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Total synthesis of Nitraraine:
Reference: Yamaguchi, R.; Hamasaki, T.; Sasaki, T.; Ohta, T. Utimoto, K.; Kozima, S.; Takaya, S. J. Org. Chem. 1993, 58, 1136. DOI
Keywords: O-H → O-SiMe2tBu • O-SiMe2tBu → O-H • Li/H → Li-Allyl • Sn-Allyl+Iminium • Iminium+Si-R • Diels-Alder, Intram • Lactam-6 • Mg-Vinyl+Epoxide • Epoxide+Mg-R • Li-Allyl → Sn-Allyl • Li/H → Li-Allyl • CarboxAmide → Amine •
Reagents: Acryloyl-Cl • Acryloyl-Cl • SiMe2tBu-Cl • AlH4-Li+ • Fluoride, R4N+ • Epoxide • Vinyl-MgX • BuLi(n) • SnMe3-Cl • Allyl-Li •

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