| Reference: | Coleman, R. S.; Lu, X.; Modolo, I. J. Am. Chem. Soc 2007, 129, 3826. DOI |
| Keywords: | O-H -> O-SO2R • O-H -> O-SiMe2tBu • Allyl-OH -> Enal • Pd/Zn-Allenyl/Propargyl+Aldehyde • Takai-Utimoto -> B-Vinyl • Pd/B-Vinyl+Vinyl-X • Suzuki coupling • Pd/Sn-Vinyl+Vinyl-X • Stille coupling • Alkyne Hydrostannation • Cu-SnR3+Alkyne • Epoxide+Na-Alkynyl • Mechanism • Alkyne Hydrozirconation • CompNu-Sn-Vinyl/B-Vinyl+Vinyl-I(Pd) • |
| Reagents: | MeSO2Cl, NEt3 • Tiglaldehyde • ZnEt2 • Pd(OAc)2 • ZrCp2ClH • I2 • SiMe2tBu-OTf • Fluoride, Bu4N+ • Epoxide • Alkynyl-Na • NH3 • CuCN • DMSO, Py·SO3 • Alkyl-B • CrCl2 • PdCl2(dppf) • AsPh3 • Vinyl-B • AsPh3 • Pd2(dba)3 • Vinyl-I • Vinyl-I • |