| Reference: | Chu-Moyer, M. Y.; Danishefsky, S. J.; Schulte, G. K. J. Am. Chem. Soc. 1994, 116, 11213. DOI |
| Keywords: | Enone -> Allyl-OH • Diol-1,2 cleavage • Lactone-5 • O-SiMe2tBu -> O-H • Aldehyde -> Alkyl-OH • O-H -> O-SiMe2tBu • Allyl-OH -> Enone • O-SiMe2tBu -> O-H • Mechanism • CompE+-Aldehyde/Lactone+Wittig • Lactone -> Lactol • CompRed-Lactone/Lactone+Al-H • Alkyl-OH -> Aldehyde • Diels-Alder, Quinone • Epoxidation, nucleophilic Enone • Wittig-methyl • Epoxidation, nucleophilic Enone • Sulfoxide-Ei -> Enone • Ketone -> Enone • Pd/Sn-Vinyl+Vinyl-X • Stille coupling • Radical reduction(C-I) • Ketone -> Vinyl-OTf • Ketone -> Ketone-α-OR • Diels-Alder, Intram • |
| Reagents: | Dioxirane • BH4-Na+ • Periodate, sodium • Acetic anhydride • Fluoride, Bu4N+ • BH4-Na+ • Cr2O7·2PyH (PDC) • H2O2, NaOH • Vinyl-Sulfide • PdCl2(PPh3)2 • Fluoride, Bu4N+ • MeSO2Cl • Epoxide • LiSnMe3 • Carbodiimide • DMAP • PPh3=CH2 • AlHiBu2 • Cr2O7·2PyH (PDC) • Photochemistry • I2 • Iodosobenzene-OAc • HSnPh3 • AIBN • AlMe3 • Dess-Martin • H2O2, NaOH • O2, tBuOK • P(OEt)3 • Dioxirane • Quinone • |