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Total synthesis of Myodesmone:
Reference: Dieter, R. K.; Dieter, J. W. Chem. Commun. 1983, 1378DOI
Keywords: ConjAdd-Silylation • Cu-Me+Enone • Ketene acetal(thio) → CarboxAcid • Cu-Alkyl+CarboxEster(thio) • CarboxEster(thio)+Cu-R • CompE+-CarboxEster/Ketone+M-R • EnolSilane → Ketone enolate • Ketone enolate+CS2 • Li-Aryl+Ketone • Enone+Li-R • CarboxAcid(dithio) → Ketene acetal(thio) •
Reagents: LiCuMe2 • SiMe3-Cl • MeLi • CS2 • LiN(SiMe3)2 • MeI • Furyl-Li • HBF4 • Alkyl-Cu • HMPA (solvent) •

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