| Reference: | Garbachio, R. M.; Stachel, S. J.; Baeschln, D. K.; Danishefsky, S. J. J. Am. Chem. Soc. 2001, 123, 10903-10908. DOI |
| Keywords: | Aryl-OMe -> Aryl-OH • O-H -> O-SiPh2tBu • Pinnick oxidation • Aldehyde -> CarboxAcid • O-H -> O-SiMe2tBu • O-SiPh2tBu -> O-H • Ketal(thio) -> Ketone • O-C(O)R -> O-H • Aryl-H -> Aryl-Cl • Mitsunobu -> Ester • Alkyl-OH -> Alkyl-OC(O)R(2°) • Li-Dithiane+Alkyl-X • Vilsmeier formylation • Aryl-H -> Aryl-CHO • RCM -> Lactone • Lactone-14 • CompE+-Alkyl-Cl/Epoxide+Li-R • CompE+-Alkyl-X/CarboxEster+Li-R • |
| Reagents: | POCl3 • BBr3 • SiPh2tBu-Cl • Epoxide • DIAD • Chlorite, sodium • SiMe2tBu-Cl • Perbenzoic acid, 3-chloro • Acetic anhydride, NEt3 • Bicarbonate, sodium • SO2Cl2 • DMF (react) • Vilsmeier reagent • Grubbs I • |