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Total synthesis of Minovine:
Reference: Ziegler, F. E.; Spitzner, E. B.. J. Am. Chem. Soc. 1973, 95, 7146. DOI
Keywords: Wittig-methyl → EnoateEster • N-Bn → N-H • Nitrile → Amine • Aldehyde → Acetal • Aldehyde enamine+EneNitrile • ConjAdd Enamine • Li/H → Li-Indole • Ketone enamine+Alkyl-X, Intram • Alkyl-X+Enamine • Hydrogenation Imine • Imine → Amine • Li-Aryl+CarboxEster • CarboxEster+Li-R • Aldehyde → Enamine • Amine-6 • Amine-5 • Diels-Alder-inverse, Enamine •
Reagents: Pyrrolyl-Li • BuLi(n) • Oxalate • Diazomethane • PPh3=CH2 • H2, Pd • Ethylene dibromide • Acrylonitrile • AlH4-Li+ • Glycol • Benzaldehyde • BuLi(n) • H2, cat • DMF (solvent) • Carbonate, sodium •

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