| Reference: | Jones, S. B.; Simmons, B.; MacMillan, D. W. C. J. J. Am. Chem. Soc. 2009, 131, 13606–13607. DOI |
| Keywords: | N-H -> N-PMB • HWE -> EneSulfide • Enal -> Allyl-OH • O-H -> O-SiEt3 • Hydrogenation Allene • O-SiEt3 -> O-H • N-PMB -> N-H • Li/H -> Li-Indole • Li-Aryl+CarboxAmide • CarboxAmide+Li-R • Radical cyclization(Alkyl) • Reductive amination, B-H • Diels-Alder, Yne • Mechanism • Amine-5 • |
| Reagents: | NaH • PMB-Cl • BuLi(n) • Formamide • NaH • P(O)(OR)2CH2-SR • BH4-Na+ • CeCl3 • SiEt3-OTf • Propiolaldehyde • BH(OAc)3-Na+ • HSntBu3 • AIBN • H2, Pd • HS-Ph • Acetic acid, trifluoro • Propiolaldehyde • Chiral catalyst • |