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Total synthesis of Mesembrane:
Reference: Pearson, W. H.; Szura, D. P.; Potich, M. J. J. Am. Chem. Soc. 1992, 114, 1329. DOI
Keywords: CarboxEster → Alkyl-OH • Alkyl-OH → Aldehyde • Aldehyde → Imine • Azide → Amine • HWE → EneSulfide • Li/Sn → Li-Amine • Azaallyl anion Cycloaddition • Amine-5 • Cyclohexane • Hydrogenolysis C-S • Staudinger •
Reagents: P(O)(OR)2CH2-SR' • AlH4-Li+ • DMSO, (COCl)2 (Swern) • PPh3 • RaNi • MeLi • MeI •

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