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Total synthesis of Lycorane:
Reference: Dong, L.; Xu, Y.-J.; Cun, L.-F.; Cui, X.; Mi, A.-Q.; Jiang, Y.-Z.; Gong, L.-Z. Org. Lett. 2005, 7, 4285. DOI
Keywords: Pictet-Spengler • Amine-6 • CarboxEster enolate+Vinyl-NO2 • Vinyl-NO2+Enolate • ConjAdd Enolate • Rh/B-Aryl+Allyl-OAc • CarboxAmide → Amine • Nitro → Amine • Lactam-5 •
Reagents: Rh(COD)2OH • BINAP • LiNiPr2 • CH2=C(OLi)(OR) • H2, RaNi • Formaldehyde • AlH4-Li+ • Acetic acid, trifluoro •

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