| Reference: | Coleman, R. S.; Walczak, M. C.; Campbell, E. L. J. Am. Chem. Soc. 2006, 127, 16038. DOI |
| Keywords: | Alkyne Hydrostannation • Sn-Vinyl -> Vinyl-I • Si-Vinyl -> Vinyl-I • In-Allyl+Amide • O-H -> O-SiEt3 • Cu-Vinyl+CarboxCl • CarboxCl+Cu-R • Vinyl-I -> Mg-Vinyl • O-SiEt3 -> O-H • N-SEM -> N-H • Vinyl-Br -> Vinyl-I • Pd/Sn-Vinyl+Aryl-X • CompNu-Sn-Vinyl/B-Vinyl+Vinyl-I(Pd) • Stille coupling • Pd/B-Vinyl+Aryl-X • Suzuki coupling • Pd/Mg-Alkynyl+Vinyl-X • Kumada coupling • Silyl-metalation Alkyne • Allyl-OH -> EnoateEster • Ozonolysis • Alkene cleavage • CompOx-Alkene/Enone+O3 • |
| Reagents: | AIBN • I2 • Vinyl-I • Alkynyl-MgX • Pd(PPh3)4 • CuCN • MnO2 • NIS • Vinyl-I • Iodide, sodium • Allyl-In • DMF (solvent) • O3 • BH4-Na+ • SiEt3-OTf • Alkyl-MgX • CuCN • Acryloyl-Cl • Vinyl-Br • Vinyl-B • Vinyl-SnR3 • Pd2(dba)3 • AsPh3 • Vinyl-B • Pd(OAc)2 • Carbonate, sodium • Acetic acid, trifluoro • |