Reference: | Lei, B.; Fallis, A. G. J. Am. Chem. Soc. 1990, 112, 4609 DOI |
Keywords: | O-H → O-C(S)OR Aldol-Li → Aldol CarboxEster enolate+Aldehyde Lactone-6 Cyclopropane alkylation Diels-Alder, Intram, Ene Bicyclo(221) Hydrogenation alkene Radical reduction(C-OR) Alkyl-OH → Alkyl-H(2°) Barton-McCombie reduction Radical reduction(C-I) Alkyl-X → Alkyl-H(2°) Ester Pyrolysis Cyclopentadienide+Ketone Mechanism Resolution ConjAdd-Alkylation Cyclopropane Fulvene+Li-R Alkyl-OH → Aldehyde Alkyl-OMe → Alkyl-I CarboxEster → Alkyl-OH O-H → O-C(O)R |
Reagents: | Epoxide Pyrrolidine MnO2 LiNiPr2 CdCl2 Cyclopentadiene BF3·OEt2 S=C(OPh)Cl HSnBu3 H2, Pd AlH4-Li+ Acetic anhydride Iodide, sodium SiMe3-Cl HSnBu3 Flash vacuum pyrolysis MeLi |