| Reference: | Welch, S. C.; Hagan, C. P.; White, D. H.; Fleming, W.P.; Trotter, J. W. J. Am. Chem. Soc. 1977, 99, 549. DOI |
| Keywords: | Ketone -> Enolether • CarboxEster -> CarboxAcid • O-THP -> O-H • Jones oxidation • Alkyl-OH -> Ketone • Ketone -> Ketone-α-Halo • CarboxAcid -> CarboxEster • Lactone-5 • Williamson esterification • Ketone -> Ketone-α-SeR • Enal -> Acetal • Meyer-Schuster Rearrangement • Lactone-6 • Ketone -> Alkyl-OH • O-H -> O-THP • Ketone enolate+CO2 • CarboxAcid -> CarboxEster • Selenoxide-Ei -> KetoEsterEnone • Aldehyde -> Enal • ConjReduct-Alkylation • CarboxEster enolate+Alkyl-X • EnoateEster ConjReduct • Robinson annulation, diketone • Ketone enamine+Enone • Enone+Enamine • Mechanism • Li-Alkynyl+Ketone • Enone+Li-R • Li/H -> Li-Alkynyl • CompE+-Ketone/Lactone+Li-R • Hydrogenation Enone • Dehydrohalogenation -> Enone • Ketone -> Enone • Claisen acylation, formate • Ketone enolate+Formate • ConjReduct Enone • ConjReduct-Acylation • CompRed-Ketone/Enone+B-H • Mechanism • |
| Reagents: | NaH • Cl-CH2-OR • Li°/NH3 • MeI • Thiolate, propyl • CrO3, H2SO4 (Jones) • Bromine • Carbonate, calcium • Bromine • Carbonate, potassium • H2, Rh • Rh(PPh3)3Cl • NaH • Formate, ethyl • SePh-Cl • Perbenzoic acid, 3-chloro • Glycol • Alkynyl-Li • H2SO4 • Wieland-Miescher • Hydroxide, potassium • Pyrrolidine • Wieland-Miescher • BH4-Na+ • DHP • Li°/NH3 • CO2 • Diazomethane • Methyl vinyl ketone • HMPA (solvent) • HMPA (solvent) • DMF (solvent) • |