| Reference: | Williams, D. R.; Patnaik, S.; Plummer, S. V. Org. Lett. 2003, 5, 5035. DOI |
| Keywords: | CarboxAmide(Evans) -> Alkyl-OH • Si-Allyl -> Allyl-Br • Acetal(thio) -> Aldehyde • O-H -> O-Me • Alkene cleavage • Ketone -> Alkyl-OH(asym) • O-H -> O-C(O)R • Enone -> Allyl-OH(asym) • O-H -> O-C(O)R • O-PMB -> O-H • Alkyl-OH -> Aldehyde • Pinnick oxidation • Aldehyde -> CarboxAcid • Cu-Vinyl+EnoateAmide(Evans) • EnoateAmide(Evans)+Cu-R • ConjAdd(asym) Cu-R • Yamaguchi lactonization • Macrolactonization • Lactone-15+ • Oxazaborolidine BH3 • Sn-Allyl+Bromoborane • Li-Dithiane+Alkyl-X • Allyl-X -> Sn-Allyl • Alkyl-OH -> Alkyl-I • Mukaiyama Aldol • Aldol-Si • B-Allyl-Corey+Aldehyde • Chiral auxiliary • |
| Reagents: | Vinyl-MgX • CuBr·SMe2 • Allyl-SiR3 • BH4-Li+ • Carbodiimide • NBS • LiSnMe3 • Allyl-SnR3 • Corey diazaborolidine • Iodosobenzene-TFA • Me3O+ X- • OsO4, NMO • Periodate, sodium • AlH4-Li+ • H3PO4 • DMAP • ZnCl2 • Corey oxazaborolidine • BH3·THF • Acetic anhydride, Py • DDQ • Dess-Martin • Chlorite, sodium • NaOMe • Benzoyl chloride, 2,4,6-trichloro • DMAP • CuBr·SMe2 • Ephedrine • Allyl-BR2 • |