| Reference: | Sun, P.; Sun, C.; Weinreb, S. M. J. Org. Chem. 2002, 67, 4337. DOI |
| Keywords: | N-H -> N-Cbz • Aldehyde -> Acetal • N-Cbz -> N-H • O-H -> O-Bn • Acetal -> Aldehyde • O-Bn -> O-H • Li/I -> Li-Alkyl • C-Si -> C-OH, Alkyl • Li-Alkyl+CarboxAmide • CarboxAmide+Li-R • Mg-Alkyl+Imonium • Imonium+Mg-R • Hydroformylation • CyanoAmine • Aldehyde -> Enamine • Amine-6 • Si-Allyl+Imonium • Imonium+Si-R • |
| Reagents: | Cu(SiMe2Ph)2Li • CuCN • CbzCl • Alkyl-Li • BuLi(tert) • BF3 • H2O2, NaHCO3 • Rh(CO)2acac • CO • Orthoformate • Na°/NH3 • NaH • TsOH • HCl, MeOH • Alkyl-MgX • BF3·OEt2 • Na°/NH3 • Cyanide, potassium • KH • Allyl-SiR3 • BF3 • |