| Reference: | Mazery, R. D.; Pullez, M.; Lopez, F.; Harutyunyan, S. R.; Minnaard, A. J.; Feringa, B. L. J. Am. Chem. Soc. 2005, 127, 9966. DOI |
| Keywords: | CarboxEster(thio) -> Aldehyde • Cu-Me+EnoateEster(thio) • ConjAdd(asym) Cu-R • Wittig-carboxymethyl -> EnoateEster • Li-Sulfoxide+Thioester • Hydrogenolysis Acyl-SR • Hydrogenolysis Acyl-SR • Alkyl-S(O)R -> Alkyl-H • CarboxEster(thio) -> Aldehyde • |
| Reagents: | MeMgBr • CuBr·SMe2 • HSiEt3, Pd • PPh3=CH-C(O)SEt • MeMgBr • CuBr·SMe2 • PPh3=CH-C(O)SEt • MeMgBr • CuBr·SMe2 • LiCH2-Sulfinyl • AlHiBu2 • ZnBr2 • RaNi • Formic acid • HSiEt3, Pd • Chiral catalyst • |