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Total synthesis of Lanceol:
Reference: Shimada, J.; Hashimoto, K.; Kim, B. H.; Nakamura, E.; Kuwajima, I J. Am. Chem. Soc. 1984, 106, 1759 DOI
Keywords: Acyloin • Cyclobutane • CarboxEster → CarboxAcid • CarboxAcid → CarboxEster • CarboxEster → Alkyl-OH • Alkyl-OH → Aldehyde • EnoateEster → Allyl-OH • Nozaki-Takai → Ene • Ketone → C=CH2 • Wittig-carboxymethyl → EnoateEster • Alkene isomerization • Mechanism • Mukaiyama Aldol • Aldol-Si •
Reagents: Na/K • SiMe3-Cl • Hydroxide, sodium • CH2Br2 • Diazomethane • AlH4-Li+ • CrO3·Py2 (Collins) • PPh3=C(Me)-CO2R • Photochemistry • AlH3 • SnCl4 • SnCl4

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