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Total synthesis of cis-Jasmone:
Reference: McMurry, J. E.; Melton, J. J. Am. Chem. Soc. 1971, 93, 5309. DOI
Keywords: Nef reaction • Alkyl-NO2 → Ketone • Nitronate+Enone • ConjAdd Nitronate • Aldol-Na → Enone • Hydrogenation Lindlar • Alkyl-X → Alkyl-NO2
Reagents: Methyl vinyl ketone • NHiPr2 • Nitrite, sodium • TiCl3 • Hydroxide, sodium • H2, Pd • DMSO (solvent) •

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