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Total synthesis of Jasmonate, Methyl- (Buchi):
Reference: Buchi, G.; Egger, B. J. Org. Chem. 1971, 36, 2021. DOI
Keywords: Alkyne → Ene-cis (Lindlar) • Michael Enone • CarboxEster enolate+Enone • ConjAdd Enolate • Mechanism • Decarbonylation • Ketone-1,3-di enolate+Alkyl-X • Alkyl-X+Enolate • Decarbonylation • Favorskii • Chelotropic, CO • Cyclopentenone • Decarboxylation malonic • Ketone → Ketone-α-Halo •
Reagents: Hydroxide, potassium • Hypochlorite, tbutyl • Malonate • H2, Pd • Carbonate, sodium •

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