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Total synthesis of Jamtine:
Reference: Padwa, A.; Danca, M. D.; Hardcastle, K. I.; McClure, M. S. J. Org. Chem. 2003, 68, 929-941. DOI
Keywords: Sulfide → Sulfoxide • O-SiMe2tBu → O-H • CarboxAmide → Thioamide • Claisen acylation, formate • CarboxEster enolate+Formate • Alkyl-OH → Alkyl-Br • Sulfoxide-Ei → EneLactam • Lactam → EneLactam • CarboxAmide enolate+Alkyl-X • Alkyl-X+Enolate • CarboxAmide → Amine • Amine-5 • Aldehyde → Enamine • Lactam-5 • Pummerer • Lactam-5 • Pictet-Spengler •
Reagents: LiNiPr2 • Periodate, sodium • NaH • Periodate, sodium • Lawesson • Me3O+ X- • PPh3, CBr4 • Formate, ethyl • BH4-Na+ • Camphor sulfonic acid •

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