| Reference: | Smith, A. B. III; Kim, D.-S. Org. Lett. 2004, 6, 1493. DOI |
| Keywords: | O-H -> O-SiMe2tBu • Hydrogenation Alkyne • Jacobson kinetic resolution • O-H -> O-SO2R • Ketal(thio) -> CH2 • Hydrogenolysis C-S • Zn-Alkynyl(asym)+Aldehyde • Aldehyde+Zn-R • N-SO2R -> N-H • Sulfonamide+Alkyl-OSO2R • CompOx-Alkene/Alkyne+Peracid • Epoxidation, peracid • Amine+Alkyl-X • Amine-5 • Amine-6 • O-SiMe2tBu -> O-H • Li-Dithiane+Epoxide • Li-Dithiane+Aziridine • |
| Reagents: | Zn(OTf)2 • Alkynyl-ZnX • SiMe2tBu-OTf • Perbenzoic acid, 3-chloro • H2, Pd • MeSO2Cl, NEt3 • Carbonate, potassium • H2, RaNi • Na(Hg) • Epoxide • Aziridine • Fluoride, Bu4N+ • |