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Total synthesis of Hirsutene:
Reference: Funk, R. L.; Bolton, G. L. J. Org. Chem. 1984, 49, 5021. DOI
Keywords: Sakurai allylation • Si-Allyl+Enone • Enone+Si-R • ConjAdd Si-Allyl • Ketone → Nitrone • Nitrone Cycloaddition • N-OR → N-H • Alkyl-OH → Ketone • Hydrogenation alkene • Cope elimination •
Reagents: TiCl4 • NMe(OH)-H • NaOEt • MeI • H2, Pd • Perbenzoic acid, 3-chloro • Bicarbonate, sodium • CrO3Cl·PyH (PCC) • H2, Pd •

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