| Reference: | Curran, D. P.; Rakiewicz, D. M. J. Am. Chem. Soc., 1985, 107, 1448. DOI |
| Keywords: | Luche reduction • Enone -> Allyl-OH • O-THP -> O-H • CarboxAcid -> Alkyl-OH • O-H -> O-Tf • Claisen-Ireland • Selenolactonization • Lactone-5 • Li-Alkynyl+Alkyl-X • Li/H -> Li-Alkynyl • Cu-Alkyl+Allyl-OAc • Selenoxide-Ei -> Allyl-OR • CompE+-Alkyl-X/Alkyl-X+Li-R • Alkyl-OH -> Alkyl-I • Radical cyclization(Alkyl) • |
| Reagents: | BH4-Na+, CeCl3 • LiNiPr2 • SePh-Cl • H2O2 • Alkyl-Li • CuBr • AlHiBu2 • Tf2O • Iodide, Bu4N+ • Fluoride, cesium • Alkynyl-Li • Li°Naphth • HSnBu3 • AIBN • |