| Reference: | Chass, D. A.; Buddhasukh, D.; Magnus, P. D. J. Org. Chem. 1978, 43, 1750. DOI |
| Keywords: | Reformatsky • CarboxEster enolate+Ketone • Ether-5 • CarboxEster -> Alkyl-OH • O-H -> O-SO2R • Fischer esterification • Nitrile -> CarboxAcid • CarboxEster -> CarboxEster-α-SePh • CarboxEster -> Alkyl-OH • O-H -> O-SO2R • Ketal -> Diol • O-H -> O-SO2R • Alkyl-OH -> Ketone • Alkyl-SO2R -> Alkyl-H • Selenoxide-Ei -> EnoateEster • CarboxEster -> EnoateEster • Cu-Me+EnoateEster • ConjAdd Cu-R • Mg-Alkyl+Ketone • Li-Sulfone+Alkyl-X • Wagner-Meerwein • Mechanism • Alkyl-X -> Alkyl-CN • Dehydration -> Ene • Epoxidation, peracid • Diol -> Ketal • Grob fragmentation • Mechanism • Li-Sulfone+Ketone • Barton remote functionalization • |
| Reagents: | Bromoacetate • Bromoacetate • Zn° • HgO • AlH4-Li+ • TsCl, Py • Cyanide, sodium • Hydroxide, sodium • BF3·OEt2 • LiNiPr2 • Periodate, sodium • LiCuMe2 • H2SO4 • Acetone (react) • AlH4-Li+ • TsCl, Py • LiCH2-Sulfonyl • TsCl, Py • CrO3·Py2 (Collins) • Al(Hg) • MeMgI • Perbenzoic acid, 3-chloro • Bicarbonate, sodium • AlH4-Li+ • Burgess reagent • Diselenide, phenyl • Acetic anhydride • Photochemistry • DMSO (solvent) • DMSO (solvent) • CuSO4 • NaH • LiCHR-Sulfonyl • DMSO (solvent) • |