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Total synthesis of Himbacene:
Reference: Tchabanenko, K.; Adlington, R. M.; Cowley, A. R.; Baldwin, J. E. Org. Lett. 2005, 7, 585. DOI
Keywords: Imine → Ketone • Amine-6 • Peterson → Enal • HWE → Enone • Reductive amination, B-H • N-H → N-Me • Diels-Alder, Intram • Li-Phosphonate+CarboxAmide • Aldehyde azaenolate+Aldehyde • Reductive amination, B-H • Amine-6 • N-H → N-Boc • N-Boc → N-H • Amine → CarboxAmide •
Reagents: ZnBr2 • Boc2O • RuO4 • Periodate, sodium • NEtiPr2 • Acetic acid, trifluoro • BH3CN-Na+ • BH3CN-Na+ • Formaldehyde • ZnCl2 • P(O)(OR)2CH2-C(O)R' •

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