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Total synthesis of Haouamine A:
Reference: Burns, N. Z., Krylova, I. N.; Hannoush, R. N.; Baran, P.S. J. Am. Chem. Soc. 2009, 31, 9172-9173 DOI. Prior paper: Baran, P.S.; Burns, N. Z. J. Am. Chem. Soc. 2006, 28, 3908-3909
Keywords: N-Boc → N-H • Pd/B-Aryl+Vinyl-X • CompE+-Vinyl-I/Alkyl-X+Ar-X(Pd) • Sulfimide-Ei → Enone • Ketone → Enone • Sulfimide-Ei → Enone • Enone enolate+Sulfinyl-Cl • N-H → N-Alkyl • Paracyclophane • Alkyl-X → Alkyl-I • O-Me → O-H (phenol) •
Reagents: B(Br)3 • BuLi(n) • B(OMe)3 • Ag2O • Iodide, sodium • Acetic acid, trifluoro • NEtiPr2 • LiN(SiMe3)2 • Imidazole •

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