| Reference: | Trost, B. M.; Pissot-Soldermann, C.; Chen, I.; Schroeder, G. M. J. Am. Chem. Soc. 2004, 126, 4480. DOI |
| Keywords: | Alkyl-OH -> Ketone • O-H -> O-Tf • Aryl-OMe -> Aryl-OH • Pd-Heck coupling • Pd-Enolate allylation(asym) • Cu-Me+Enone-β-OR • ConjAdd Cu-R • Alkene cleavage • CompE+-Aldehyde/Vinyl-X+Li-R • Hydrogenation Alkene • Vinyl-OTf -> Vinyl-H • Ketone -> Vinyl-OTf • Ketone -> Ketone-1,2-di • Aryl-H -> Aryl-Br • |
| Reagents: | Trost bisphosphine • Chiral catalyst • LiNiPr2 • LiNiPr2 • Tf2NPh • LiCuMe2 • OsO4, NMO • Dess-Martin • BCl3 • Pd, formic acid • Tf2O • Pd(OAc)2 • H2, Ir • Pd/C • BBr3 • SeO2 • NBS • Periodate, sodium • Allyl-OAc • |