image

Total synthesis of Gypsy moth sex pheromone:
Reference: Koumaglo, K.; Chan, T. H. Tetrahedron Lett. 1984, 25, 717. DOI
Keywords: Li-Allyl+Alkyl-X • Alkyl-X+Li-R • Si-Vinyl → I-Vinyl • Si-Vinyl → I-Vinyl • Pd/Zn-Alkyl+Vinyl-X • Negishi coupling • Epoxidation, peracid • Li/H → Li-Allyl-X •
Reagents: Allyl-SiR3 • BuLi, KOtBu • Allyl-Li • Vinyl-SiR3 • ICl • HI • ICl • Alkyl-ZnX • Perbenzoic acid, 3-chloro • I2 • Pd(PPh3)4

Syntheses Home