| Reference: | Jayathilaka, L. P.; Deb, M.; Standaert, R. F. Org. Lett. 2004, 6, 3659. DOI |
| Keywords: | Li/Br -> Li-Vinyl Li-Vinyl -> Mg-Vinyl N-S(O)R -> N-H O-tBu -> O-H Li-Vinyl -> Mg-Vinyl Mg-Vinyl+Imine Sulfinamide, chiral Chiral auxiliary |
| Reagents: | Glyoxalate Sieves Glyoxalate BuLi(tert) MgBr2 HCl, MeOH Acetic acid, trifluoro Sulfinamide Vinyl-Li |