| Reference: | Corey, E. J.; Kang, M. C.; Desai, M. C.; Ghosh, A. K.; Houpis, I. N. J. Am. Chem. Soc. 1988, 110, 649-651. DOI |
| Keywords: | Ketone -> Vinyl-OTf • Hydroboration Alkyne • Alkyne -> Ene-cis • Orthoester -> CarboxAcid • Pd-Sonogashira • Ketone enamine+Aldehyde • Aldol-enamine -> Enone • Acetal -> Acetal(thio) • Alkyl-OH -> Aldehyde • CompOx-Alkyl-OH/Sulfide+CrO3 • Acetal(thio) -> Aldehyde • Acetal(thio) -> Acetal • Acetal -> Acetal • Allylic oxidation -> Enone • Kornblum oxidation • O-H -> O-SiMe2tBu • Alkene -> Diol-1,2 • O-SiMe2tBu -> O-H • Cu-Alkyl(3°)+Enone • ConjAdd-Silylation • Mukaiyama Aldol • Aldol-Si • Lactone -> Lactone-α-OH • CarboxEster enolate+Ketone • Epoxide -> Diol • Lactol -> Lactone • Lactone-5 • CompOx-Lactol/Alkyl-OH+I2 • CompE+-Ketone/Lactone+Enolate • CompRed-Alkyne/Alkene+B-H • Epoxidation, nucleophilic Enone • Protecting group - CarboxAcid • CarboxAcid -> CarboxCl • Baeyer-Villiger • Lactone-5 • Ketene Cycloaddition • Cyclobutane • |
| Reagents: | HCl • CuCN • SiMe3-Cl • TiCl4 • LiNiPr2 • Tf2NPh • Pd(PPh3)4 • CuI • NH2Pr • BHCy2 • Acetic acid • H2O2 • HCl • TiCl4 • Cr2O7·2PyH (PDC) • Periodate • Camphor sulfonic acid • LiNEt2 • Oxaziridine • Camphor sulfonic acid • NBS • AgNO3 • TsOH·Py • Hydroperoxide, trityl • P(OMe)3 • LiNiPr2 • Camphor sulfonic acid • SiMe2tBu-OTf • OsO4 • I2 • Carbonate, calcium • BF3·OEt2 • Oxalyl chloride • NBu3 • Hydroperoxide, trityl • Hydroxide, sodium • |