| Reference: | Ataraschi, S.; Choi, J-K.; Ha, D-C.; Hart, D.J.; Kuzmich, D.; Lee, C-S.; Ramesh, S.; Wu, S.C. J. Am. Chem. Soc., 1997, 119, 6226-6241 DOI |
| Keywords: | Diels-Alder, Maleic anhydride • Ketone -> Ketal • O-THP -> O-H • Ozonolysis • Mg-Aryl+Carboxester • CarboxEster+Mg-R • O-H -> O-Me • N-H -> N-C(O)R • Ozonolysis • O-Bn -> O-H • Alkyl-OH -> Aldehyde • Wittig-ketomethyl -> Enone • Ketone -> Enolsilane • Selenoxide-Ei -> Ene • Mitsunobu -> SeR • CarboxImide+BH • CarboxAmide enolate+Alkyl-X • Wittig-carboxymethyl -> EnoateEster • Ketone enolate+Isocyanate • Radical cyclization(Aryl) • Acetal -> Ether • Petasis reagent • Radical cyclization(Alkyl) • |
| Reagents: | PPh3 • LiNiPr2 • SiMe3-Cl • TsOH • Selenocyanate, o-nitrophenyl • PBu3 • H2O2 • BH4-Na+ • NaH • LiNiPr2 • Cl-CH2-OR • O3 • Formate, ethyl • HS-Ph • TsOH • PhMgBr • MeI • DMSO (solvent) • KH • TsOH • Acetic anhydride • DMAP • HSnBu3 • TsOH • O3 • HCl, H2O • HSiEt3 • Acetic acid, trifluoro • AIBN • BBr3 • Dess-Martin • TiCp2Me2 • HSnBu3 • AIBN • |