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Total synthesis of Fukinone:
Reference: Marshall, J. A.; Cohen, G. M. Tetrahedron Lett 1970, 3865. DOI
Keywords: Alkyl-OH → Ketone • O-H → O-C(O)R • Allylic oxidation → Enone • ConjAdd Cu-R • Cu-Me+Enone • Enone+Cu-Me • Wolff-Kishner • Ketone → CH2 • Ketone → EnolCarboxylate • Epoxidation, Peracid • Ketone → Ketone-α-OR • Li-Vinyl+Ketone • Ketone+Li-Vinyl • Alkyl-OH → Ketone-α-OR • Ketone-α-OR → Ketone •
Reagents: CrO4Na2 • Acetic anhydride • LiCuMe2 • Hydrazine • Glycol • CrO3, H2SO4 (Jones) • LiCPh3 • Acetic anhydride • Vinyl-Li • DMSO, Py·SO3 (Parikh-Doering) • Acetic anhydride • Ca°/NH3

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