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Total synthesis of Fukinone New:
Reference: Marshall, J. A.; Cohen, G. M. Tetrahedron Lett 1970, 3865. DOI
Keywords: Alkyl-OH -> Ketone • O-H -> O-C(O)R • Allylic oxidation -> Enone • ConjAdd Cu-R • Cu-Me+Enone • Enone+Cu-Me • Wolff-Kishner • Ketone -> CH2 • Ketone -> Enolacetate • Epoxidation, Peracid • Ketone -> Ketone-α-OR • Li-Vinyl+Ketone • Ketone+Li-Vinyl • Alkyl-OH -> Ketone-α-OR • Ketone-α-OR -> Ketone •
Reagents: CrO4Na2 • Acetic anhydride • LiCuMe2 • Hydrazine • Glycol • CrO3, H2SO4 (Jones) • LiCPh3 • Acetic anhydride • Vinyl-Li • DMSO, Py·SO3 • Acetic anhydride • Ca°/NH3

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